Saturday, January 17, 2009

Ionic Air Purifier Technologies - Solid Science or Slick Commercial Marketing?

Introduction

Ionic air purifiers hold the promise of clean air, purified of all known harmful contaminants that threaten our health. Air is made impure by substances unseen by our naked eye. The weapons against such are very likely to be invisible to our eyes as well. Intuitively, the logic is compelling. But these days, finding a simple and quick solution is rare. Googling the subject unearths a ton of controversy. It is quite clear that the urge to rush out and buy an ionic air purifier must be suppressed at the moment. Product safety must take precedence over effectiveness in choosing an ionic air purifier.

The recent China melamine saga that killed infants also serves as a reminder to us that in buying into any technology or any product, all claims by manufacturers and distributors must be examined to the fullest extent that our resources permit. This is even more critical when the key reactive agent is unseen to the human eye. Investigating ionic air purifier technologies falls within this ambit as the reactive agents are invisible ions.

This article is an overview of existing ionic air purifier technology in the marketplace. As laypersons, I believe we have to adopt a back-to-basics approach to try and understand the technologies. The current key trend appears to be the creation of a potent invisible defence shield against airborne molecular contaminants that threaten our well-being. The dominant global health threat under the scrutiny of scientists is the avian flu virus.

Types of Ionic Air Purifier Technologies

Broadly speaking, air purification technologies can be deployed in either passive or active modes. Passive typically means that impure air is drawn into the air purifier for the reactive agents to work on before re-emerging as cleaned air into the environment. Active generally means dispersive processes by which the impure air is penetrated and purified by the reactive agents. Combinations of both passive and active modes are often found in many types of ionic air purifiers.

In the global market today, ionic air purifier technologies include the following categories:

(A) Ion generator - positive and negative ions
(B) Ion generator - negative ions only
(C) Photocatalytic Oxidation (POC)
(D) Electrostatic filter
(E) Combos

Ion Generator - Positive and Negative Ions

This combination of positive and negative ions appears to show the most promise for the future of ionic air purifier technology. Pioneered by the Japanese corporate giant, Sharp Corporation, they are known as plasmacluster ions.

Sharp Corporation's marketing efforts focus on the ability of plasmacluster ions to surround and cling on to harmful airborne bacteria and viruses. When this happens, hydroxyl is produced. Hydroxyl, also known as nature's detergent, is a powerful reactive species that plucks out hydrogen molecules from the organic structure of these airborne particulates thereby destroying them. Harmless by-products, mainly water, are generated by this chemical reaction.

This technology uses a differential ion generator, comprising a positive and a negative ion generator which can be powered in alternate cycles to control the type of ions generated.

Advocates of the positive and negative ions combination claim that a balance of both these ion types is to be found in places like waterfalls and pristine forests, i.e. this is the actual state in nature. In contrast, proponents of negative ions technology insist that negative ions fill natural habitats and that the presence of positive ions is harmful. In this regard, I have yet to find independent scientific studies as evidence for the contradictory claims of both camps.


Ion Generator - Negative Ions

The traditional ionic air purifier produces only negative ions. This technology appears to have the main market share currently but is facing a serious challenge from Sharp's plasmacluster positive and negative ions technology.

It is claimed that nearly all harmful airborne particulates like dust, smoke and bacteria etc have a positive charge. Negative ions from the air purifier attach themselves to these particulates until they get weighed down and fall to the ground. Thereafter, simple vacuuming removes these impurities. Detractors of negative ion technology believe that the "overweight" particulates on the ground are not destroyed and that the mere act of walking on them re-contaminates the air.

In addition, there appears to be several methods of producing the negative ions. This is important because different methods produce different by-products, some of which may be harmful. These methods include:

(1) Water method - this employs what is known as the waterfall or Lenard Effect. Onto an electrically-charged metal plate, water droplets are splashed. This splits the water droplets, a process in which large numbers of negative ions are produced. No harmful by-products result from using the water method to produce ions.

(2) Electron radiation method - this is based on a single negative discharge electrode needle. Millions of negatively-charged electrons are produced when a high voltage pulse is applied to the electrode. This method does not result in ozone being produced. This is due to the application of a "smaller" energy pulse.

(3) Corona discharge method - this is based on a dual electrode model, a sharp metal electrode and a flat electrode. High voltage is applied between the electrodes. This causes the movement of electrons between the electrodes thereby ionising the air in between them. This method has been criticised for the production of harmful by-products like ozone and nitride oxide.

Photocatalytic Oxidation (POC)

This technology is commonly applied in a passive mode. The key reactive purifying agent is hydroxyl, nature's detergent.

Germicidal ultraviolet (UV) light is commonly shone on a catalyst (usually titanium oxide) to produce hydroxyl, oxygen and peroxide, all of which are potent oxidising agents that are very effective at destroying the organic structure of micro-organisms and gaseous volatile organic compounds.

Comprehensive defence is the key strength of POC technology. Proponents of this technology claim that POC inactivates ALL categories of indoor pollution, including:

(1) airborne particulates i.e. dust, pet dander, plant pollen, sea salts, tobacco smoke, industrial and car pollution, etc

(2) bioaerosols i.e. contagious or infectious biological compounds (e.g. viruses and pathogenic bacteria) or non-infectious and non-contagious (e.g. non-pathogenic bacteria, molds, cell debris)

(3) volatile organic compounds (VOCs) i.e. gaseous odours and chemicals - toluene, chloroform, hexane, ethanol, formaldehyde, ethylene etc, all common emissions from everyday products of our modern home.

POC technology has been criticised for relying on hydroxyl which are believed to attack with equal tenacity the organic structures that make up molecular contaminants and our lung tissue, nose membranes and eye cornea.

Electrostatic Filter

This technology appears to have originated in heavy industries which produced abundant pollutants. In the most common electrostatic filter arrangement, there is a porous dielectric material positioned between two electrodes. Dielectric materials do not conduct electricity while metallic electrodes are excellent conductors that transmit and receive electricity.

Contaminated air is drawn into the electrostatic puriifer and made to pass over the dielectric material which acts like a sieve. Electrostatic forces between the electrodes causes airborne particulates i.e.smoke contaminants, dust, etc, to stick to the dielectric surface. Purified air is pushed out of the purifier and re-circulated.

Quite often, an ion source is placed before the electrostatic filter to impart an electric charge to the airborne particulates. The impurities, now carrying an electrical charge, stick more effectively to the dielectric material.

The general criticism of ionisation technology applies to electrostatic filters as well i.e. that harmful ozone is a by-product.

Combo Ionic Air Purifiers

To cater to the various adherents and critics of the diverse technologies, combos incorporate all or some of the above types of technologies. Combos may include:

(1) adsorptive materials such as activated carbon or oxygenated charcoal (known for its extremely porous large surface area) are added to POC technology to enhance the removal of VOCs;

(2) oxidizing catalysts like titanium oxide are coated on various components of all types of air purifiers to enhance VOC elimination;

(3) reducing catalysts such as manganese dioxide are coated near the exit outlets of many air purifiers to reduce reactive species like ozone and nitric oxide which may be harmful;

(4) generating ions by differing methods such as using microwave, UV light, radio frequency waves, and direct current;

(5) tweaking the specifications of any ionic air purifier technology so as to attain the well-known HEPA status without actually using HEPA filters.

Obviously, the process of selecting the most efficient and effective ionic air purifier involves analysing a deluge of information. The safety issues of each technology will need much more investigation. I have also not examined in greater depth the claims of each technology. It is natural to want to quickly want something that promises to improve the air quality in your homes, offices, factories, schools etc. But I urge you to do your homework and don't forget to visit me for updates as I continue my search for the ideal ionic air purifier.

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